克里格反應
克里格反應（Criegee reaction）[1]指鄰二醇被四乙酸鉛氧化，經過環狀酯中間體，鄰二醇的碳－碳鍵斷裂，醇羥基轉化為相應的醛、酮。反應是定量的，通常在乙酸或苯溶液中進行，可用於鄰二醇的定量分析。
參見
[編輯]參考資料
[編輯]- ^ R. Criegee, Ber. 64, 260 (1931).
- ^ R. Criegee in Newer Methods of Preparative Organic Chemistry vol. 1 (Interscience, New York, 1948) pp 12-20.
- ^ H. O. House, Modern Synthetic Reactions (W. A. Benjamin, Menlo Park, California, 2nd ed., 1972) pp 359-387.
- ^ K. W. Bentley in Elucidation of Organic Structures by Physical and Chemical Methods pt. 2, K. W. Bentley, G. W. Kirby, Eds. (Wiley, New York, 2nd ed., 1973) pp 169-177.
- ^ S. Hatakeyama, H. Akimoto, Res. Chem. Intermed. 20, 503-524 (1994).
- ^ S. Chandrasekhar, C. D. Roy, J. Chem. Soc. Perkin Trans. 2 1994, 2141.
- ^ R. Ponec et al., J. Org. Chem. 62, 2757 (1997).
- ^ R. M. Goodman, Y. Kishi, J. Am. Chem. Soc. 120, 9392 (1998).