五均三甲苯基五铜

五均三甲苯基五铜
识别
CAS号	88760-64-9
SMILES	[Cu+]1[C-]=2([Cu+][C-]=3([Cu+][C-]=4([Cu+][C-]=5([Cu+][C-]1=6C(=CC(=CC6C)C)C)C(=CC(=CC5C)C)C)C(=CC(=CC4C)C)C)C(=CC(=CC3C)C)C)C(=CC(=CC2C)C)C;
性质
化学式	C45H55Cu5
摩尔质量	913.65 g·mol−1
外观	黄色晶体
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

五均三甲苯基五铜是一种有机铜化合物，化学式为C₄₅H₅₅Cu₅，或简写为Cu₅Mes₅或(CuMes)₅，其中Mes表示均三甲苯基。该化合物最初于1981年被报道。^[1]它可由均三甲苯基溴化镁（维基数据所列：Q82213729）和氯化亚铜在四氢呋喃中反应制得。^[2]它和双(三氟甲磺酰基)胺（HNTf₂）反应，可以得到[Cu(MesH)₂][Cu(NTf₂)₂]。^[3]

参考文献

^ Michael Stollenz; Franc Meyer. Mesitylcopper – A Powerful Tool in Synthetic Chemistry. Organometallics 2012, 31, 22, 7708–7727. doi:10.1021/om3007689.
^ Edouard Marc Meyer; et al. Polynuclear aryl derivatives of Group 11 metals. Synthesis, solid state-solution structural relationship, and reactivity with phosphines. Organometallics 1989, 8, 4, 1067–1079. doi:10.1021/om00106a031.
^ Marion Stricker; et al. Copper(I) and Silver(I) Bis(trifluoromethanesulfonyl)imide and Their Interaction with an Arene, Diverse Olefins, and an NTf2−-Based Ionic Liquid. Chem Eur J. 2013. 19 (3): 1042-1057. doi:10.1002/chem.201201740

[1] Michael Stollenz; Franc Meyer. Mesitylcopper – A Powerful Tool in Synthetic Chemistry. Organometallics 2012, 31, 22, 7708–7727. doi:10.1021/om3007689.

[2] Edouard Marc Meyer; et al. Polynuclear aryl derivatives of Group 11 metals. Synthesis, solid state-solution structural relationship, and reactivity with phosphines. Organometallics 1989, 8, 4, 1067–1079. doi:10.1021/om00106a031.

[3] Marion Stricker; et al. Copper(I) and Silver(I) Bis(trifluoromethanesulfonyl)imide and Their Interaction with an Arene, Diverse Olefins, and an NTf2−-Based Ionic Liquid. Chem Eur J. 2013. 19 (3): 1042-1057. doi:10.1002/chem.201201740

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