1-氟丙烷
外觀
1-氟丙烷 | |
---|---|
別名 | 氟代正丙烷 正丙基氟 PrF |
識別 | |
CAS號 | 460-13-9 |
性質 | |
化學式 | C3H7F |
摩爾質量 | 62.09 g·mol−1 |
密度 | 0.7818 g·cm−3[1] |
熔點 | −159 °C(114 K)[1] |
沸點 | −2.3 °C(270.8 K)(768 mmHg)[2] −2.5 °C(270.6 K)[1] |
溶解性(水) | 難溶 |
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。 |
1-氟丙烷是一種有機化合物,化學式為C3H7F,是一種氣體。它可以環丙烷和氟化氫鉀在四氟化硅存在下反應得到。[3]它發生消除反應的能量為58.3 kcal·mol−1(激波管法測得)。[4]
參考文獻
[編輯]- ^ 1.0 1.1 1.2 Aristid V. Grosse, Richard C. Wackher, Carl B. Linn. Physical Properties of the Alkyl Fluorides and a Comparison of the Alkyl Fluorides with the Other Alkyl Halides and with the Alkyls of the Elements of Period II.. The Journal of Physical Chemistry. 1940-03, 44 (3): 275–296 [2022-04-16]. ISSN 0092-7325. doi:10.1021/j150399a002. (原始內容存檔於2021-06-28) (英語).
- ^ Walter F. Edgell, L. Parts. Synthesis of Alkyl and Substituted Alkyl Fluorides from p-Toluenesulfonic Acid Esters. The Preparation of p-Toluenesulfonic Acid Esters of Lower Alcohols 1. Journal of the American Chemical Society. 1955-09, 77 (18): 4899–4902 [2022-04-16]. ISSN 0002-7863. doi:10.1021/ja01623a065 (英語).
- ^ Masanori Tamura, Motonari Shibakami, Shigeru Kurosawa, Takashi Arimura, Akira Sekiya. Hydrofluorination of unsaturated compounds with solid potassium hydrogen fluoride in the presence of silicon tetrafluoride at room temperature. Journal of the Chemical Society, Chemical Communications. 1995, (18): 1891 [2022-04-16]. ISSN 0022-4936. doi:10.1039/c39950001891 (英語).
- ^ P. Cadman, M. Day, A. W. Kirk, A. F. Trotman-Dickenson. Activation energies for the elimination of hydrogen fluoride from alkyl fluorides obtained by the activated molecule and competitive shock-tube techniques. Journal of the Chemical Society D: Chemical Communications. 1970, (4): 203 [2022-04-16]. ISSN 0577-6171. doi:10.1039/c29700000203 (英語).