氧氮化磷
| 氧氮化磷 | |
|---|---|
| 别名 | 氮化磷酰 |
| 识别 | |
| CAS号 | 23369-45-1 
|
| SMILES |
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| 性质 | |
| 化学式 | NOP |
| 摩尔质量 | 60.98 g·mol−1 |
| 外观 | 无色固体 |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
氧氮化磷是一种无机化合物，化学式为OPN，属于氧氮化物。它是二氧化硅的等电子体，具有多种晶型。[1]
合成及应用
[编辑]氧氮化磷可由六氯环三氮磷烷在氨-氧混合气氛中的热解制得。[2]它也是O2PNCO的分解产物之一。[3]
参考文献
[编辑]- ^ Zhen-Long Lv, Shi-Jie Lv, Kai-Tong Wang, Hong-Ling Cui. Electronic, Elastic, Piezoelectric, and Infrared Properties of 2D Phosphorus Oxynitride by First Principles. Physica Status Solidi B: Basic Solid State Physics (2024), 261(5), 2400074. doi:10.1002/pssb.202400074.
- ^ 2.0 2.1 Lukai Luo; et al. Amorphous phosphorus oxynitride as a robust catalyst for steam-free direct dehydrogenation of ethylbenzene to styrene: effect of calcination temperature. Catal. Sci. Technol., 2024,14, 728-734. doi:10.1039/D3CY01315D.
- ^ Bifeng Zhu; et al. Phosphenic isocyanate (O2PNCO): gas-phase generation, characterization, and photodecomposition reactions. Chem. Commun., 2022,58, 10703-10706.
- ^ Simon D. Kloß; Wolfgang Schnick. LiPr2P4N7O3: Structural Diversity of Oxonitridophosphates Accessed by High-Pressure Metathesis. Inorg. Chem. 2018, 57, 7, 4189–4195. doi:10.1021/acs.inorgchem.8b00455.