1,4-二乙烯基苯

1,4-二乙烯基苯
别名	1,4-二乙烯苯
识别
CAS号	105-06-6
性质
化学式	C10H10
摩尔质量	130.19 g·mol−1
密度	1.5805 g·cm−3（20 °C）; 0.913 g·cm−3（40 °C）
熔点	31 °C（304 K）
沸点	52 °C（325 K）（4 torr）
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

1,4-二乙烯基苯是一种有机化合物，化学式为C₁₀H₁₀。它可由1,4-二(溴甲基)苯和甲醛在碳酸钾和三苯基膦的存在下反应得到。^[3]其它制法还包括1,4-二苯甲醛和三苯基亚甲基磷的反应^[4]、1,4-二碘苯和三乙烯基铟的反应^[5]、1,4-二乙炔基苯的加氢反应^[6]1,4-二乙苯的脱氢反应^[7]等。

参考文献

^ Yakovich, N. I.; Khcheyan, Kh. E.; Pavlichev, A. F.; Kondrat'eva, N. N.; Izrael, L. B. High-purity divinylbenzenes. 1969. GB 1149475.
^ ^2.0 ^2.1 ^2.2 Lespieau; Deluchat. p-Divinylbenzene and p-diacetenylbenzene. Compt. rend., 1930. 190: 683-684.
^ Jiang, Min; Yang, Haijun; Lefebvre, Quentin; Su, Jihu; Fu, Hua. Olefination of Alkyl Halides with Aldehydes by Merging Visible-Light Photoredox Catalysis and Organophosphorus Chemistry. iScience. 2018, 6: 102–113. ISSN 2589-0042. doi:10.1016/j.isci.2018.07.011.
^ Monika Ludwiczak, Mariusz Majchrzak, Bogdan Marciniec, Maciej Kubicki. Highly stereoselective synthesis of novel trans-thiophenylene-silylene-vinylene-arylene molecular and macromolecular compounds. Journal of Organometallic Chemistry. 2011-04, 696 (7): 1456–1464 [2021-06-30]. doi:10.1016/j.jorganchem.2011.01.020. （原始内容存档于2020-02-25）（英语）.
^ Miguel A. Pena, José Pérez Sestelo, Luis A. Sarandeses. New Synthetic Applications of Indium Organometallics in Cross-Coupling Reactions. Synthesis. 2005, 2005 (03): 485–492 [2021-06-30]. ISSN 0039-7881. doi:10.1055/s-2004-834945. （原始内容存档于2018-06-03）（德语）.
^ Wienhöfer, Gerrit; Westerhaus, Felix A.; Jagadeesh, Rajenahally V.; Junge, Kathrin; Junge, Henrik; Beller, Matthias. Selective iron-catalyzed transfer hydrogenation of terminal alkynes. Chemical Communications. 2012, 48 (40): 4827. ISSN 1359-7345. doi:10.1039/c2cc31091k.
^ Bachmann, Reinhard; Siekiera, Karl Heinz; Wegewitz, Kurt; Feldhaus, Reinhard; Vieweg, Hans Guenther; Schoenfeld, Dieter; Zielke, Erich; Anders, Klaus. Preparation of divinylbenzene by dehydrogenation of diethylbenzene（德文）. 1990. DD 282815 A7.

[1] Yakovich, N. I.; Khcheyan, Kh. E.; Pavlichev, A. F.; Kondrat'eva, N. N.; Izrael, L. B. High-purity divinylbenzenes. 1969. GB 1149475.

[Lespieau-2] 2.0 ^2.1 ^2.2 Lespieau; Deluchat. p-Divinylbenzene and p-diacetenylbenzene. Compt. rend., 1930. 190: 683-684.

[3] Jiang, Min; Yang, Haijun; Lefebvre, Quentin; Su, Jihu; Fu, Hua. Olefination of Alkyl Halides with Aldehydes by Merging Visible-Light Photoredox Catalysis and Organophosphorus Chemistry. iScience. 2018, 6: 102–113. ISSN 2589-0042. doi:10.1016/j.isci.2018.07.011.

[4] Monika Ludwiczak, Mariusz Majchrzak, Bogdan Marciniec, Maciej Kubicki. Highly stereoselective synthesis of novel trans-thiophenylene-silylene-vinylene-arylene molecular and macromolecular compounds. Journal of Organometallic Chemistry. 2011-04, 696 (7): 1456–1464 [2021-06-30]. doi:10.1016/j.jorganchem.2011.01.020. （原始内容存档于2020-02-25）（英语）.

[5] Miguel A. Pena, José Pérez Sestelo, Luis A. Sarandeses. New Synthetic Applications of Indium Organometallics in Cross-Coupling Reactions. Synthesis. 2005, 2005 (03): 485–492 [2021-06-30]. ISSN 0039-7881. doi:10.1055/s-2004-834945. （原始内容存档于2018-06-03）（德语）.

[6] Wienhöfer, Gerrit; Westerhaus, Felix A.; Jagadeesh, Rajenahally V.; Junge, Kathrin; Junge, Henrik; Beller, Matthias. Selective iron-catalyzed transfer hydrogenation of terminal alkynes. Chemical Communications. 2012, 48 (40): 4827. ISSN 1359-7345. doi:10.1039/c2cc31091k.

[7] Bachmann, Reinhard; Siekiera, Karl Heinz; Wegewitz, Kurt; Feldhaus, Reinhard; Vieweg, Hans Guenther; Schoenfeld, Dieter; Zielke, Erich; Anders, Klaus. Preparation of divinylbenzene by dehydrogenation of diethylbenzene（德文）. 1990. DD 282815 A7.

[1]

[2]

[3]

[4]

[5]

[6]

[7]