硫氰酸铜

硫氰酸铜
别名	Cupric thiocyanate
识别
CAS号	15192-76-4
PubChem	10103751
ChemSpider	8279278
SMILES	C(#N)[S-].C(#N)[S-].[Cu+2];
性质
化学式	Cu(SCN)2
摩尔质量	179.71 g/mol g·mol⁻¹
外观	黑色粉末
密度	2.47 g/cm3
熔点	180 °C分解
磁化率	0.66·10−3 cm3/mol
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

硫氰酸铜是一种配位聚合物，化学式为Cu(SCN)₂。^[1]它是黑色固体，缓慢在潮湿空气中分解。^[2]它最初在1838年被报道，但于2018年结构才被表征。^[3]其结构包含链状Cu(NCS)₂，由弱Cu-S-Cu键连接。^[1]它可由铜盐浓溶液和可溶性硫氰酸盐在水中反应制得。^[2]^[3]通过快速干燥，可以得到纯的Cu(SCN)₂。低浓度及长时间的反应会产生硫氰酸亚铜。^[4]

参考文献

^ ^1.0 ^1.1 ^1.2 ^1.3 ^1.4 Cliffe, Matthew J.; Lee, Jeongjae; Paddison, Joseph A. M.; Schott, Sam; Mukherjee, Paromita; Gaultois, Michael W.; Manuel, Pascal; Sirringhaus, Henning; Dutton, Siân E.; Grey, Clare P. Low-dimensional quantum magnetism in Cu(NCS)₂ : A molecular framework material. Physical Review B. 2018-04-25, 97 (14): 144421. ISSN 2469-9950. doi:10.1103/PhysRevB.97.144421 （英语）.
^ ^2.0 ^2.1 ^2.2 Hunter, J. A.; Massie, W. H. S.; Meiklejohn, J.; Reid, J. Thermal rearrangement in copper(II) thiocyanate. Inorganic and Nuclear Chemistry Letters. 1969-01-01, 5 (1): 1–4. ISSN 0020-1650. doi:10.1016/0020-1650(69)80226-6.
^ ^3.0 ^3.1 Claus, C. Beiträge zur näheren Kenntniss der Schwefelcyanmetalle. Journal für Praktische Chemie. 1838, 15 (1): 401–411. ISSN 1521-3897. doi:10.1002/prac.18380150142 （英语）.
^ Smith, D. L.; Saunders, V. I. Preparation and structure refinement of the 2H polytype of β-copper(I) thiocyanate. Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry. 15 March 1982, 38 (3): 907–909. doi:10.1107/S0567740882004361.

[:0-1] 1.0 ^1.1 ^1.2 ^1.3 ^1.4 Cliffe, Matthew J.; Lee, Jeongjae; Paddison, Joseph A. M.; Schott, Sam; Mukherjee, Paromita; Gaultois, Michael W.; Manuel, Pascal; Sirringhaus, Henning; Dutton, Siân E.; Grey, Clare P. Low-dimensional quantum magnetism in Cu(NCS)₂ : A molecular framework material. Physical Review B. 2018-04-25, 97 (14): 144421. ISSN 2469-9950. doi:10.1103/PhysRevB.97.144421 （英语）.

[:2-2] 2.0 ^2.1 ^2.2 Hunter, J. A.; Massie, W. H. S.; Meiklejohn, J.; Reid, J. Thermal rearrangement in copper(II) thiocyanate. Inorganic and Nuclear Chemistry Letters. 1969-01-01, 5 (1): 1–4. ISSN 0020-1650. doi:10.1016/0020-1650(69)80226-6.

[:1-3] 3.0 ^3.1 Claus, C. Beiträge zur näheren Kenntniss der Schwefelcyanmetalle. Journal für Praktische Chemie. 1838, 15 (1): 401–411. ISSN 1521-3897. doi:10.1002/prac.18380150142 （英语）.

[Smith-4] Smith, D. L.; Saunders, V. I. Preparation and structure refinement of the 2H polytype of β-copper(I) thiocyanate. Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry. 15 March 1982, 38 (3): 907–909. doi:10.1107/S0567740882004361.

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